You can only *replace* User Interface (UI), you will need a pack which contains files that replace each part of the UI. I think there are 2 ways to do that:
1) you import it using a specific path (in similar manner like icons) - you can replace this way your selected UI (e.g. night elf UI only)
2) you use Game Interface option and replace it there, but that will either replace all UIs or human UI only I think