Try moving the tileset all the way to the left (in the advanced -> modify tileset panel).
This will let your tileset get under all other tilesets (so that border should be gone).
Don't forget to save/re-load the map once this is done!
Edit: didn't see your second request, sorry.
The tileset's path is "TerrainArt\BlackCitadel\Citadel_DarkTiles.blp", although I don't think that is the problem.
If the path was wrong, you wouldn't see the tileset at all.